Mass spectra of 9H-xanthene and 9H-thioxanthene derivatives.
نویسندگان
چکیده
منابع مشابه
Methyl 9H-xanthene-9-carboxylate
The title compound, C(15)H(12)O(3), was obtained unintentionally as the by-product of an attempted recrystallization from methanol of propantheline bromide, an anti-muscarinic drug. The xanthone unit is folded, with a dihedral angle of 24.81 (9)° between the benzene rings. The ester substituent adopts a trans staggered conformation, with a C-C-O-C torsion angle of 178.4 (1)°. The mol-ecules pac...
متن کامل9-Methoxy-9-(2-methoxyphenyl)-9H-xanthene
In the title compound, C(21)H(18)O(3), the xanthene system and the meth-oxy-phenyl ring are practically orthogonal with a dihedral angle between their mean planes of 89.27 (3)°. The meth-oxy group attached to the phenyl ring makes a C-O-C-C torsion angle of 11.56 (18)°. In the crystal, mol-ecules are linked by C-H⋯O inter-actions into chains along [010]. Weak C-H⋯π inter-actions also occur.
متن کامل4,5-Dibromo-2,7-di-tert-butyl-9,9-dimethyl-9H-thioxanthene
In the title compound, C(23)H(28)Br(2)S, the thioxanthene unit is twisted, showing a dihedral angle of 29.3 (5)° between the benzene rings. When projected along [001], the packing shows two types of channels. The crystal studied was a racemic twin.
متن کامل(E)-2-Methoxy-9-(2-methoxy-9H-xanthen-9-ylidene)-9H-xanthene
The title compound, C28H20O4, was synthesized by a bimolecular Zn-HCl reduction in glacial acetic acid using the meth-oxy-substituted xanthone as a starting material. The crystal structure shows that the 2,2'-meth-oxy-bixanthenyl-idene unit is an E-type conformation anti-folded conformer. The mol-ecule lies on an inversion center. The meth-oxy group is almost coplanar with the attached benzene ...
متن کاملMethyl 7-methoxy-9-oxo-9H-xanthene-2-carboxylate
The crystal structure of the title compound, C(16)H(12)O(5), is stabilized by C-H⋯O hydrogen bonds and C=O⋯π inter-actions; π-π inter-actions are also present. With respective average deviations from planarity of 0.003 (2) and 0.002 (1) Å, the xanthone and ester fragments are oriented at an angle of 2.8 (2)° with respect to each other. The mean planes of the xanthone skeleton lie either paralle...
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ژورنال
عنوان ژورنال: Chemical and Pharmaceutical Bulletin
سال: 1989
ISSN: 0009-2363,1347-5223
DOI: 10.1248/cpb.37.1074